The title compound, [PdPtCl(C3H5)(C6H10N2S2)(C17H14NP)]·CHCl3, was obtained by deprotonation of the initial platinum(II) complex of the dithioxamide and subsequent reaction with [Pd([eta]3-C3H5)([mu]-Cl)]2. Both metal atoms exhibit a square-planar coordination geometry, with the two planes forming a dihedral angle of 21.7 (2)°. The dithioxamide bis-chelating bridge is flat.
(2002). (η3-Allyl-2k3C)(chloro-1kCl)(µ-N,N'-diethyldithioxamidato-1:2k4S,S':N,N') [diphenyl(2-pyridyl)phosphine-1kP] palladium (II) platinum (II) chloroform solvate [journal article - articolo]. In ACTA CRYSTALLOGRAPHICA. SECTION C, CRYSTAL STRUCTURE COMMUNICATIONS. Retrieved from http://hdl.handle.net/10446/166163
(η3-Allyl-2k3C)(chloro-1kCl)(µ-N,N'-diethyldithioxamidato-1:2k4S,S':N,N') [diphenyl(2-pyridyl)phosphine-1kP] palladium (II) platinum (II) chloroform solvate
Rosace, G.
2002-01-01
Abstract
The title compound, [PdPtCl(C3H5)(C6H10N2S2)(C17H14NP)]·CHCl3, was obtained by deprotonation of the initial platinum(II) complex of the dithioxamide and subsequent reaction with [Pd([eta]3-C3H5)([mu]-Cl)]2. Both metal atoms exhibit a square-planar coordination geometry, with the two planes forming a dihedral angle of 21.7 (2)°. The dithioxamide bis-chelating bridge is flat.| File | Dimensione del file | Formato | |
|---|---|---|---|
|
2002 (g3-Allyl-2j3C)(chloro-1jCl)(l-N,N0- diethyldithioxamidato-1:2j4S,S0:N,N0)- [diphenyl(2-pyridyl)phosphine-1jP]- palladium(II)platinum(II) chloroform solvate.pdf
Solo gestori di archivio
Versione:
publisher's version - versione editoriale
Licenza:
Licenza default Aisberg
Dimensione del file
94.47 kB
Formato
Adobe PDF
|
94.47 kB | Adobe PDF | Visualizza/Apri |
Pubblicazioni consigliate
Aisberg ©2008 Servizi bibliotecari, Università degli studi di Bergamo | Terms of use/Condizioni di utilizzo
