Methoxy- and ethoxycarbonyl radicals were easily produced by silver-catalyzed decarboxylation of methyl and ethyl esters of oxalic acid by S2O8=. They were utilized for the alkoxycarbonylation of heteroaromatic bases with high yield and selectivity in a two-phase system, suitable for practical applications.
(1992). A novel convenient and selective alkoxycarbonylation of heteroaromatic bases by oxalic acid monoesters [journal article - articolo]. In TETRAHEDRON LETTERS. Retrieved from http://hdl.handle.net/10446/230229
A novel convenient and selective alkoxycarbonylation of heteroaromatic bases by oxalic acid monoesters
Fontana, Francesca;
1992-01-01
Abstract
Methoxy- and ethoxycarbonyl radicals were easily produced by silver-catalyzed decarboxylation of methyl and ethyl esters of oxalic acid by S2O8=. They were utilized for the alkoxycarbonylation of heteroaromatic bases with high yield and selectivity in a two-phase system, suitable for practical applications.File allegato/i alla scheda:
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