The asymmetric oxidation of the functionalized sulfides with sodium metaperiodate in the presence of a catalytic amount of bovine serum albumin (BSA) affords the corresponding sulfoxides with enantiomeric excess (ee) up to 69.3%. The influence of the molecular structure of the substrate and of the pH value of the buffer solution on the asymmetric synthesis has also been examined. © 1985, American Chemical Society. All rights reserved.
(1985). Asymmetric Periodate Oxidation of Functionalized Sulfides Catalyzed by Bovine Serum Albumin [journal article - articolo]. In JOURNAL OF ORGANIC CHEMISTRY. Retrieved from https://hdl.handle.net/10446/231749
Asymmetric Periodate Oxidation of Functionalized Sulfides Catalyzed by Bovine Serum Albumin
Fontana, Francesca;
1985-01-01
Abstract
The asymmetric oxidation of the functionalized sulfides with sodium metaperiodate in the presence of a catalytic amount of bovine serum albumin (BSA) affords the corresponding sulfoxides with enantiomeric excess (ee) up to 69.3%. The influence of the molecular structure of the substrate and of the pH value of the buffer solution on the asymmetric synthesis has also been examined. © 1985, American Chemical Society. All rights reserved.| File | Dimensione del file | Formato | |
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