The halogenation of adamantane by CBrCl3 with Gif-Barton and metalloporphyrin catalysis is compared with classical free-radical halogenations (Br2, NBS, t-BuOCl, R2NCl) and with the behaviour of simple alkanes (n-hexane, 2,3-dimethylbutane, cyclohexane); the free-radical mechanism is discussed.
(1994). Regio- and chemo-selectivity of adamantane halogenation by Gif-Barton and metalloporphyrin catalysis and by classical free-radical reactions [journal article - articolo]. In TETRAHEDRON LETTERS. Retrieved from https://hdl.handle.net/10446/231890
Regio- and chemo-selectivity of adamantane halogenation by Gif-Barton and metalloporphyrin catalysis and by classical free-radical reactions
Fontana, Francesca;
1994-01-01
Abstract
The halogenation of adamantane by CBrCl3 with Gif-Barton and metalloporphyrin catalysis is compared with classical free-radical halogenations (Br2, NBS, t-BuOCl, R2NCl) and with the behaviour of simple alkanes (n-hexane, 2,3-dimethylbutane, cyclohexane); the free-radical mechanism is discussed.File allegato/i alla scheda:
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Regio- and chemo-selectivity of adamantane halogenation by Gif-Barton and metalloporphyrin catalysis and by classical free-radical reactions - ScienceDirect.pdf
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