New general syntheses, based on free-radical oxidative alkylation, acylation and arylation of acrylonitrile, in the presence of Bu(t)O(2)H, are reported; the concept of the peroxy group as a pseudohalide is suggested to explain these new reactions.
(1995). Hydroperoxides as pseudohalides: oxidation, oxidative alkylation, acylation and arylation of acrylonitrile [journal article - articolo]. In JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. Retrieved from https://hdl.handle.net/10446/232218
Hydroperoxides as pseudohalides: oxidation, oxidative alkylation, acylation and arylation of acrylonitrile
Fontana, Francesca;
1995-01-01
Abstract
New general syntheses, based on free-radical oxidative alkylation, acylation and arylation of acrylonitrile, in the presence of Bu(t)O(2)H, are reported; the concept of the peroxy group as a pseudohalide is suggested to explain these new reactions.File allegato/i alla scheda:
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Hydroperoxides as pseudohalides_ oxidation, oxidative alkylation, acylation and arylation of acrylonitrile - Journal of the Chemical Society, Chemical Communications (RSC Publishing).pdf
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