Alkyl, α-oxyalkyl and acyl radical intermediates in the oxidation of alkanes, ethers and aldehydes by dimethyldioxirane are trapped by protonated quinolines and a free-radical chain is suggested for the α-acetoxylation of ketones.
(1995). Trapping of free-radicals in the oxidation of ethers, aldehydes and alkanes by dimethyldioxirane [journal article - articolo]. In TETRAHEDRON LETTERS. Retrieved from https://hdl.handle.net/10446/232220
Trapping of free-radicals in the oxidation of ethers, aldehydes and alkanes by dimethyldioxirane
Fontana, Francesca;
1995-01-01
Abstract
Alkyl, α-oxyalkyl and acyl radical intermediates in the oxidation of alkanes, ethers and aldehydes by dimethyldioxirane are trapped by protonated quinolines and a free-radical chain is suggested for the α-acetoxylation of ketones.File allegato/i alla scheda:
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