The oxidation of alkanes by dimethyldioxirane (DMD) in the presence of CBrCl3 provides strong evidence that free-radicals are involved in the reaction; enthalpic and polar effects and an "oxygen rebound" mechanism are suggested to explain the exceptional oxidation selectivity.
(1995). Free-radicals in the oxidation and halogenation of alkanes by dimethyldioxirane: an oxygen rebound mechanism [journal article - articolo]. In TETRAHEDRON LETTERS. Retrieved from https://hdl.handle.net/10446/232225
Free-radicals in the oxidation and halogenation of alkanes by dimethyldioxirane: an oxygen rebound mechanism
Fontana, Francesca;
1995-01-01
Abstract
The oxidation of alkanes by dimethyldioxirane (DMD) in the presence of CBrCl3 provides strong evidence that free-radicals are involved in the reaction; enthalpic and polar effects and an "oxygen rebound" mechanism are suggested to explain the exceptional oxidation selectivity.File allegato/i alla scheda:
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