The oxidation of alkanes by dimethyldioxirane (DMD) in the presence of CBrCl3 provides strong evidence that free-radicals are involved in the reaction; enthalpic and polar effects and an "oxygen rebound" mechanism are suggested to explain the exceptional oxidation selectivity.

(1995). Free-radicals in the oxidation and halogenation of alkanes by dimethyldioxirane: an oxygen rebound mechanism [journal article - articolo]. In TETRAHEDRON LETTERS. Retrieved from https://hdl.handle.net/10446/232225

Free-radicals in the oxidation and halogenation of alkanes by dimethyldioxirane: an oxygen rebound mechanism

Fontana, Francesca;
1995-01-01

Abstract

The oxidation of alkanes by dimethyldioxirane (DMD) in the presence of CBrCl3 provides strong evidence that free-radicals are involved in the reaction; enthalpic and polar effects and an "oxygen rebound" mechanism are suggested to explain the exceptional oxidation selectivity.
articolo
Minisci, Francsco.; Zhao, Lihua; Fontana, Francesca; Bravo, Anna
(1995). Free-radicals in the oxidation and halogenation of alkanes by dimethyldioxirane: an oxygen rebound mechanism [journal article - articolo]. In TETRAHEDRON LETTERS. Retrieved from https://hdl.handle.net/10446/232225
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10446/232225
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