Adamantane is oxidised by MCPBA in a free-radical process, whose selectivity is discussed; by this method, cyclohexanol can be directly oxidised to caprolactone.
(1996). 'Oxenoid' oxygen insertion vs. a radical mechanism in the oxidation of alkanes and alcohols: The case of aromatic peracids [journal article - articolo]. In CHEMICAL COMMUNICATIONS. Retrieved from https://hdl.handle.net/10446/232370
'Oxenoid' oxygen insertion vs. a radical mechanism in the oxidation of alkanes and alcohols: The case of aromatic peracids
Fontana, Francesca;
1996-01-01
Abstract
Adamantane is oxidised by MCPBA in a free-radical process, whose selectivity is discussed; by this method, cyclohexanol can be directly oxidised to caprolactone.File allegato/i alla scheda:
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‘Oxenoid’ oxygen insertion vs. a radical mechanism in the oxidation of alkanes and alcohols_ the case of aromatic peracids - Chemical Communications (RSC Publishing).pdf
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