Metalloporphyrins, a chemical model of cytochrome P450, catalyze the oxidation of phenols with the para-position free to the corresponding p-quinones. Evidences of a free-radical mechanism are reported, including the results obtained with p-cresol.
(1996). A free-radical mechanism in a novel metalloporphyrin-catalyzed oxidation of phenols by t-BuOOH [journal article - articolo]. In CHEMISTRY LETTERS. Retrieved from https://hdl.handle.net/10446/232373
A free-radical mechanism in a novel metalloporphyrin-catalyzed oxidation of phenols by t-BuOOH
Fontana, Francesca;
1996-01-01
Abstract
Metalloporphyrins, a chemical model of cytochrome P450, catalyze the oxidation of phenols with the para-position free to the corresponding p-quinones. Evidences of a free-radical mechanism are reported, including the results obtained with p-cresol.File allegato/i alla scheda:
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A Free-Radical Mechanism in a Novel Metalloporphyrin-Catalyzed Oxidation of Phenols by t-BuOOH _ Chemistry Letters _ CSJ Journals.pdf
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