Trapping of l-butoxy radical by ethyl vinyl ether represents a strong evidence of the freeradical mechanism of the Gil reaction, in contrast with Barton's interpretation. The reaction has been developed from a synthetic point of view for new selective substitutions of heteroaromatic bases and quinones. The fundamental role of the polar effects in determining the selectivity is discussed.
(1996). Polar effects in free-radical reactions. new homolytic substitutions of heteroaromatic bases and quinones by ethyl vinyl ether and hydroperoxides [journal article - articolo]. In GAZZETTA CHIMICA ITALIANA. Retrieved from https://hdl.handle.net/10446/232389
Polar effects in free-radical reactions. new homolytic substitutions of heteroaromatic bases and quinones by ethyl vinyl ether and hydroperoxides
Fontana, Francesca;
1996-01-01
Abstract
Trapping of l-butoxy radical by ethyl vinyl ether represents a strong evidence of the freeradical mechanism of the Gil reaction, in contrast with Barton's interpretation. The reaction has been developed from a synthetic point of view for new selective substitutions of heteroaromatic bases and quinones. The fundamental role of the polar effects in determining the selectivity is discussed.| File | Dimensione del file | Formato | |
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Polar effects in free-radical reactions. New homolytic substitutions of heteroaromatic bases and quinones by ethyl vinyl ether and hydroperoxides.pdf
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