Silanes are oxidised to silanols by molecular oxygen, under N-hydroxyphthalimide and Co(II) catalysis, under very mild conditions and in good yields and selectivily. The reaction proceeds through the superimposition of a redox chain to a free-radical chain reaction.
(2002). A new, highly selective, free-radical aerobic oxidation of silanes to silanols catalysed by N-hydroxyphthalimide under mild conditions [letter - lettera]. In SYNLETT. Retrieved from https://hdl.handle.net/10446/241950
A new, highly selective, free-radical aerobic oxidation of silanes to silanols catalysed by N-hydroxyphthalimide under mild conditions
Fontana, Francesca;
2002-01-01
Abstract
Silanes are oxidised to silanols by molecular oxygen, under N-hydroxyphthalimide and Co(II) catalysis, under very mild conditions and in good yields and selectivily. The reaction proceeds through the superimposition of a redox chain to a free-radical chain reaction.File allegato/i alla scheda:
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